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Design of bio-oil additives via molecular signature descriptors using a multi-stage computer-aided molecular

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 2,   Pages 168-182 doi: 10.1007/s11705-021-2056-8

Abstract: Direct application of bio-oil from fast pyrolysis as a fuel has remained a challenge due to its undesirablethis work, computer-aided molecular design tools were developed to design optimal solvents to upgrade bio-oilFinally, phase stability analysis was conducted to evaluate the stability of the solvent-oil blend.As a result, optimal solvents that improve the solvent-oil blend properties while displaying low environmental

Keywords: computer-aided molecular design     bio-oil additives     molecular signature descriptor    

Production of renewable fuels by blending bio-oil with alcohols and upgrading under supercritical conditions

Sainab Omar, Suzanne Alsamaq, Yang Yang, Jiawei Wang

Frontiers of Chemical Science and Engineering 2019, Volume 13, Issue 4,   Pages 702-717 doi: 10.1007/s11705-019-1861-9

Abstract: The work studied a non-catalytic upgrading of fast pyrolysis bio-oil by blending under supercriticalCharacterisation of the bio-oil and the upgraded bio-oils was carried out including moisture content,The GCMS analysis indicated that the supercritical methanol reaction removed the acids in the bio-oilconsequently the pH increased from 2.39 in the crude bio-oil to 4.04 after the supercritical methanolSimply blending crude bio-oil with isopropanol was effective in increasing the C and H content, reducing

Keywords: bio-oil     blending     supercritical     upgrading     characterisation    

Distillation Characteristics of Bio-oil and Its Application

Yang Xulai,Lu Qiang,Zhu Xifeng

Strategic Study of CAE 2007, Volume 9, Issue 11,   Pages 110-114

Abstract:

Distillate from atmospheric distillation of bio-oil accounts for about50%Bio-oil can't be applied for requiring complete evaporation before combustion, but can be employedThe composition of bio-oil is complicated, phenols derived from lignin can be extracted by vacuum distillationAnd the distillation method can also be used to improve the ov erall fuel properties of bio-oil such

Keywords: bio-oil     distillation     phenols     up-grading of bio-oil    

A review on catalytic & non-catalytic bio-oil upgrading in supercritical fluids

Sainab Omar, Yang Yang, Jiawei Wang

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 1,   Pages 4-17 doi: 10.1007/s11705-020-1933-x

Abstract: This review article summarizes the key published research on the topic of bio-oil upgrading using catalyticThe precious metal catalysts Pd, Ru and Pt on various supports are frequently chosen for catalytic bio-oilesterification, which leads to improvements in liquid yield, heating value, and pH of the upgraded bio-oilOn the other hand, SCFs have been effectively used to upgrade crude bio-oil without a catalyst.

Keywords: bio-oil     upgrading     supercritical     review    

Research on combustion characteristics of bio-oil from sewage sludge

Rui LI, Baosheng JIN, Xiangru JIA, Zhaoping ZHONG, Gang XIAO, Xufeng FU

Frontiers of Chemical Science and Engineering 2009, Volume 3, Issue 2,   Pages 161-166 doi: 10.1007/s11705-009-0057-0

Abstract: Combustion characteristics of bio-oil from sewage sludge were investigated using thermogravimetry (TG

Keywords: bio-oil from sewage sludge     fast pyrolysis     combustion characteristics     TG-FT-IR     kinetic    

Property, Up-grading and Utilization of Bio-oil from Biomass

Zhu Xifeng,Zheng Jilu,Guo Qingxiang,Zhu Qingshi

Strategic Study of CAE 2005, Volume 7, Issue 9,   Pages 83-88

Abstract:

Element content, chemical composition, stability, viscosity and heat value of bio-oil are analyzedSome new technologies to refine and to utilize bio-oil are introduced such as directly catalyzing bio-oilvapor, and adding surfactants into bio-oil,so that it can be used directly in diesel engine.The catalysts and their effects on the refining and utilization of bio-oil are discussed.

Keywords: biomass     bio-oil     fuel property     up-grading    

Recent advances in the catalytic pyrolysis of biomass

Changwei HU, Yu YANG, Jia LUO, Pan PAN, Dongmei TONG, Guiying LI

Frontiers of Chemical Science and Engineering 2011, Volume 5, Issue 2,   Pages 188-193 doi: 10.1007/s11705-010-1015-6

Abstract: catalysts could decrease the pyrolysis temperature, increase the conversion of biomass and the yield of bio-oil, and change the distribution of the pyrolytic liquid products then improve the quality of the bio-oil

Keywords: biomass     liquefaction     catalysis     bio-oil     process intensification    

Highly selective catalytic hydrodeoxygenation of guaiacol to cyclohexane over Pt/TiO

Zhong HE,Xianqin WANG

Frontiers of Chemical Science and Engineering 2014, Volume 8, Issue 3,   Pages 369-377 doi: 10.1007/s11705-014-1435-9

Abstract: Catalysts Pt/TiO and NiMo/Al O are highly active and selective for the hydrodeoxygenation of guaiacol in a fixed bed reactor at 300 °C and 7.1 MPa, leading to the hydrogenation of aromatic ring, followed by demethylation and dehydroxylation to produce cyclohexane. For a complete hydrodeoxygenation of guaiacol, metal sites and acid sites are required. NiMo/Al O and Pt/Al O are more active and selective for cyclohexane formation as compared with Pt/TiO at 285 °C and 4 MPa. However, Pt/TiO is stable while the other two catalysts deactivate due to the nature and amount of coke formation during the reaction.

Keywords: Pt/TiO2     NiMo/Al2O3     Pt/Al2O3     bio-oil     hydrodeoxygenation    

Ball milling promoted direct liquefaction of lignocellulosic biomass in supercritical ethanol

Chunyan Yang, Xiaoliang Yuan, Xueting Wang, Kejing Wu, Yingying Liu, Changjun Liu, Houfang Lu, Bin Liang

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 4,   Pages 605-613 doi: 10.1007/s11705-019-1841-0

Abstract: work, ball milling was applied for the pretreatment of lignocellulose to obtain high conversion and bio-oilAn increased bio-oil yield of 59.2% was obtained for the ball milled camphorwood sawdust at 300°C, comparedThe obtained bio-oil had a high phenolic content, as analyzed by gas chromatography-mass spectrometry

Keywords: ball milling     lignocellulose     supercritical ethanol     liquefaction     bio-oil    

Development of Biomass Pyrolysis Set and Its Experimental Research

Zhu Xifeng,Zheng Jilu,Lu Qiang,Guo Qingxiang,Zhu Qingshi

Strategic Study of CAE 2006, Volume 8, Issue 10,   Pages 89-93

Abstract: .Experimental result shows that the developed pyrolysis set is available to convert biomass into bio-oiland all biomass have an optimal temperature for maximum bio-oil yields.For instance, bio-oil yields of sawdust, rice husk, corn stalk and cotton stalk are 63% ,53% ,57% andThe analysis indicates that the calorific value of bio-oil is about 17 MJ/kg and bio-oil is a mixtureThe research also shows that drying biomass can effectively reduce the moisture in bio-oil, and the bio-oil

Keywords: biomass     pyrolysis     bio-oil    

Combustion characteristics and kinetics of bio-oil

Ruixia ZHANG, Zhaoping ZHONG, Yaji HUANG

Frontiers of Chemical Science and Engineering 2009, Volume 3, Issue 2,   Pages 119-124 doi: 10.1007/s11705-009-0068-x

Abstract: The combustion characteristics of bio-oils derived from rice husk and corn were studied by thermogravimetryin air and nitrogen atmosphere, we analyzed the combustion characteristics of different kinds of bio-oilsin different atmospheres and worked out the combustion kinetics parameters of the bio-oil, providingreliable base data for the burning of bio-oil.The thermogravimetry indicated that the combustion process of bio-oil was divided into three stages.

Keywords: bio-oil     combustion characteristics     combustion kinetics    

Oilfield Chemical Additives in Drilling: Current Applications & Development Trend

Liu Rushan,Su Changming

Strategic Study of CAE 2002, Volume 4, Issue 5,   Pages 88-92

Abstract:

This paper summarizes the current research and applications of oil field chemical additives in drillingFor the development trend of oilfield chemical additives, it is, guided by new oilfield chemistry theory

Keywords: oil field additives     drilling & completion fluid     reservoir protectiori     multifunctional polymers    

Oil alternative strategies and mid-long term development goals of bio-energy

Li Shizhong

Strategic Study of CAE 2011, Volume 13, Issue 6,   Pages 101-107

Abstract:

The guarantee feedstock resources for developing bio-energy in ChinaMain bio-energy products and biomass conversion techniques were reviewed, such as fuel ethanol, biodiesel, biogas and bio-pelletes etc.The goals of developing bio-energy at different stages in our nation from now to 2050 were introduced

Keywords: bio-energy     feedstock guarantee     bio-energy product     developing goal    

Electrochemical Biorefinery Towards Chemicals Synthesis and Bio-Oil Upgrading from Lignin Review

Rui Hu, Yuying Zhao, Chen Tang, Yan Shi, Gang Luo, Jiajun Fan, James H. Clark, Shicheng Zhang

Engineering 2023, Volume 27, Issue 8,   Pages 178-198 doi: 10.1016/j.eng.2022.10.013

Abstract: Recent works suggested a promising pathway for lignin depolymerization and lignin-derived bio-oil upgradingThis review presents the progress on chemicals synthesis and bio-oil upgrading from lignin by an electrochemical

Keywords: Lignin     Electrochemical biorefinery     Reaction pathway     Electron transfer mechanism     Kinetics     Thermodynamics    

Theoretical insights into influence of additives on sulfamethoxazole crystal growth kinetics and mechanisms

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10,   Pages 1503-1515 doi: 10.1007/s11705-022-2294-4

Abstract: In this work, the influence of the initial chemical potential gradient, stirring speed, and polymer type on sulfamethoxazole (SMX) crystal growth kinetics was systematically investigated through density functional theory (DFT) calculations, experimental measurements and the two-step chemical potential gradient model. To investigate the influence of different conditions on the thermodynamic driving force of SMX crystal growth, SMX solubilities in different polymer solutions were studied. Four model polymers effectively improved SMX solubility. It was further found that polyvinylpyrrolidone (PVP) and hydroxypropyl methyl cellulose (HPMC) played a crucial role in inhibiting SMX crystal growth. However, polyethylene glycol (PEG) promoted SMX crystal growth. The effect of the polymer on the crystal growth mechanisms of SMX was further analyzed by the two-step chemical potential gradient model. In the system containing PEG 6000, crystal growth is dominated by the surface reaction. However, in the system containing PEG 20000, crystal growth is dominated by both the surface reaction and diffusion. In addition, DFT calculations results showed that HPMC and PVP could form strong and stable binding energies with SMX, indicating that PVP and HPMC had the potential ability to inhibit SMX crystal growth.

Keywords: insoluble drugs     polymer     inhibition crystallization     crystal growth kinetics     DFT calculations    

Title Author Date Type Operation

Design of bio-oil additives via molecular signature descriptors using a multi-stage computer-aided molecular

Journal Article

Production of renewable fuels by blending bio-oil with alcohols and upgrading under supercritical conditions

Sainab Omar, Suzanne Alsamaq, Yang Yang, Jiawei Wang

Journal Article

Distillation Characteristics of Bio-oil and Its Application

Yang Xulai,Lu Qiang,Zhu Xifeng

Journal Article

A review on catalytic & non-catalytic bio-oil upgrading in supercritical fluids

Sainab Omar, Yang Yang, Jiawei Wang

Journal Article

Research on combustion characteristics of bio-oil from sewage sludge

Rui LI, Baosheng JIN, Xiangru JIA, Zhaoping ZHONG, Gang XIAO, Xufeng FU

Journal Article

Property, Up-grading and Utilization of Bio-oil from Biomass

Zhu Xifeng,Zheng Jilu,Guo Qingxiang,Zhu Qingshi

Journal Article

Recent advances in the catalytic pyrolysis of biomass

Changwei HU, Yu YANG, Jia LUO, Pan PAN, Dongmei TONG, Guiying LI

Journal Article

Highly selective catalytic hydrodeoxygenation of guaiacol to cyclohexane over Pt/TiO

Zhong HE,Xianqin WANG

Journal Article

Ball milling promoted direct liquefaction of lignocellulosic biomass in supercritical ethanol

Chunyan Yang, Xiaoliang Yuan, Xueting Wang, Kejing Wu, Yingying Liu, Changjun Liu, Houfang Lu, Bin Liang

Journal Article

Development of Biomass Pyrolysis Set and Its Experimental Research

Zhu Xifeng,Zheng Jilu,Lu Qiang,Guo Qingxiang,Zhu Qingshi

Journal Article

Combustion characteristics and kinetics of bio-oil

Ruixia ZHANG, Zhaoping ZHONG, Yaji HUANG

Journal Article

Oilfield Chemical Additives in Drilling: Current Applications & Development Trend

Liu Rushan,Su Changming

Journal Article

Oil alternative strategies and mid-long term development goals of bio-energy

Li Shizhong

Journal Article

Electrochemical Biorefinery Towards Chemicals Synthesis and Bio-Oil Upgrading from Lignin

Rui Hu, Yuying Zhao, Chen Tang, Yan Shi, Gang Luo, Jiajun Fan, James H. Clark, Shicheng Zhang

Journal Article

Theoretical insights into influence of additives on sulfamethoxazole crystal growth kinetics and mechanisms

Journal Article